报告主持人：Prof. Masakazu Ampo（教授、红宝石hbs0022平台&日本大阪公立大学）

报告摘要:

Hydrogen peroxide (H2O2) has attracted much attention as an environmentally  friendly oxidant  as  well  as  a  promising  liquid  fuel.  Photocatalytic  process  is  a  potentially sustainable method for H2O2 production. However, the activity  is still  limited, and new materials  and  approaches  for  photocatalytic H2O2  production  are  highly  desired. Our group  demonstrated  that  application  of metal-organic  framework  (MOF) materials  for photocatalytic H2O2 production via oxygen reduction for the first time [1]. Thanks to the advantages  of  the  unprecedented  design  flexibility  of MOFs, we  developed  the MOF materials  to  improve  the  photocatalytic  activity  for  H2O2  production  by  the  linker functionalization  and  the  missing-linker  defects  in  the  MOF  framework,  and  the utilization of a noble two-phase reaction system using hydrophobic MOFs [1-8].  

[1] Y. Isaka, H. Yamashita, et al., Chem. Comm., 2018, 54, 9270–9273.

[2] Y. Isaka, H. Yamashita, et al., Angew. Chem. Int. Ed., 2019, 58, 5402–5406.

[3] Y. Kawase, H. Yamashita, et al., Chem. Comm., 2019, 55, 6743–6746.  

[4] X. Chen, H. Yamashita, et al., J. Mater. Chem. A, 2020, 8, 1904–1910.

[5] X. Chen, H. Yamashita, et al., J. Mater. Chem. A, 2021, 9, 2815–2821.

[6] Y. Kondo, H. Yamashita, et al., J. Phys. Chem. C, 2021, 125, 27909–27918.

报告人简介：

Hiromi Yamashita 教授自2004年起就职于大阪大学（Osaka University），曾获日本催化协会, 日本光化学协会, 日本石油协会, 日本金属与材料协会等奖项。